The value of ΔG° at 181.0 °C for the formation of calcium chloride from calcium metal and chlorine gas is ________ kJ/mol. At 25.0 °C for this reaction, ΔH° is -795.8 kJ/mol, ΔG° is -748.1 kJ/mol, and ΔS° is -159.8 J/K.

Respuesta :

Answer:

[tex]\Delta G^{0}[/tex] at 181.0 [tex]^{0}\textrm{C}[/tex] is -723.3 kJ/mol.

Explanation:

We know, [tex]\Delta G^{0}=\Delta H^{0}-T\Delta S^{0}[/tex]

where, T is temperature in kelvin.

Let's assume [tex]\Delta H^{0}[/tex] and [tex]\Delta S^{0}[/tex] does not change in the temperature range 25.0 [tex]^{0}\textrm{C}[/tex]  - 181.0 [tex]^{0}\textrm{C}[/tex].

[tex]181.0^{0}\textrm{C}[/tex] = (273+181.0) K = 454.0 K

Hence, at 181.0 [tex]^{0}\textrm{C}[/tex], [tex]\Delta G^{0}=(-795.8kJ/mol)-[(454.0 K)\times (-159.8\times 10^{-3}kJ/K.mol)][/tex]

        = -723.3 kJ/mol