A solution was prepared by dissolving 40.0 g of kcl in 225 g of water. part a calculate the mass percent of kcl in the solution. express your answer with the appropriate units. 15.1 {\rm \\%} calculate the mole fraction of the ionic species kcl in the solution.

Respuesta :

Explanation:

(a)   According to the given data, mass of the solution will be calculated as follows.

          Mass of solution = Mass of KCl + Mass of water

                                      = (40 + 225) g

                                      = 265 g

Therefore, (m/m)% of KCl will be calculated as follows.

           (m/m)% of KCl = [tex]\frac{\text{mass of KCl}}{\text{mass of solution}} \times 100[/tex]    

                                   = [tex]\frac{40}{265} \times 100[/tex]

                                   = 15.09%

Hence, mass percent of KCl in the solution is 15.09%.

(b)    Now, we will calculate the mole fraction of ionic species present in KCl  in the solution are follows.

Molar mass of KCl is 74.55 g/mol.

                Moles of KCl = [tex]\frac{mass}{\text{molar mass}}[/tex]

                                      = [tex]\frac{40 g}{74.55 g/mol}[/tex]

                                      = 0.536 mol

or,                                   = 0.54 mol

As, molar mass of water is 18 g/mol. Hence, moles of water will be calculated as follows.

           Moles of [tex]H_{2}O[/tex] = [tex]\frac{mass}{\text{molar mass}}[/tex]

                                      = [tex]\frac{225 g}{18 g/mol}[/tex]

                                      = 12.5 mol

So, total number of moles = moles of KCl + moles of [tex]H_{2}O[/tex]

                                           = (0.54 + 12.5) mol

                                           = 13.04 mol

Calculate the mole fraction of KCl in the solution as follows.

              Mole fraction = [tex]\frac{\text{moles of KCl}}{\text{total moles}}[/tex]

                                     = [tex]\frac{0.54 mol}{13.04 mol}[/tex]

                                     = 0.041

Therefore, mole fraction of the ionic species KCl in the solution is 0.041.

A. The mass percent of KCl in the solution is 15.1%

B. The mole fraction of the ionic species KCl in the solution is 0.041

A. Determination of the mass percent of KCl in the solution.

Mass of KCl = 40 g

Mass of water = 225 g

Mass of solution = 40 + 225

Mass of solution = 265 g

Percentage of KCl =?

[tex]Percentage = \frac{mass of solute}{mass of solution} * 100\\\\= \frac{40}{265} * 100\\\\[/tex]

= 15.1%

Therefore, the mass percent of KCl in the solution is 15.1%

B. Determination of the mole fraction of the ionic species KCl in the solution

  • We'll begin by calculating the number of mole in 40 g of KCl.

Mass of KCl = 40 g

Molar mass of KCl = 39 + 35.5 = 74.5 g/mol

Mole of KCl =?

Mole = mass / molar mass

Mole of KCl = 40 / 74.5

Mole of KCl = 0.537 mole

  • Next, we shall determine the number of mole in 225 g of water, H₂O.

Mass of H₂O = 225 g

Molar mass of H₂O = (2×1) + 16 = 18 g/mol

Mole of H₂O =?

Mole = mass / molar mass

Mole of H₂O = 225 / 18

Mole of H₂O = 12.5 mole

  • Finally, we shall determine the mole fraction of the ionic species KCl.

Mole of KCl = 0.537 mole

Mole of H₂O = 12.5 mole

Total mole = 0.537 + 12.5 = 13.037 mole

Mole fraction of KCl =?

Mole fraction = mole of element / total mole

Mole fraction of KCl = 0.537 / 13.037

Mole fraction of KCl = 0.041

Therefore, the mole fraction of the ionic species KCl is 0.041

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