Respuesta :
Given reaction:
Mg(OH)2(s) + 2HCl(g) → MgCl2(s) + 2H2O(g)
Formula:
ΔS°rxn = ∑nS°(products) - ∑nS°(reactants)
= [S°(MgCl2) + 2S°(H2O)] -[S°(Mg(OH)2 + 2S°(HCl)]
= [89.3+2(188.7)] - [63.22+2(186.80] = 29.88 J/K
Thus, the standard entropy change for the reaction is around 30 J/K
The standard entropy change for the given reaction obtained at 25 °C is 29.88 J/K
Data obtained from the question
- Mg(OH)₂(s) + 2HCl(g) → MgCl₂(s) + 2H₂O(g)
- Change in entropy (ΔS°rxn) =?
Standard molar entropy
The standard molar entropy for each entity in the reaction is given below:
- Entropy of Mg(OH)₂(s) = 63.22 J/K
- Entropy of HCl(g) = 186.80 J/K
- Entropy of MgCl₂(s) = 89.3 J/K
- Entropy of H₂O(g) = 188.7 J/K
How to determine the change in entropy
Mg(OH)₂(s) + 2HCl(g) → MgCl₂(s) + 2H₂O(g)
ΔS°rxn = ∑nS°(products) - ∑nS°(reactants)
ΔS°rxn = [S°(MgCl₂) + 2S°(H₂O)] – [S°(Mg(OH)₂ + 2S°(HCl)]
ΔS°rxn = [89.3 + 2(188.7)] – [63.22 + 2(186.80]
ΔS°rxn = [89.3 + 377.4] – [63.22 + 373. 6]
ΔS°rxn = 466.7 – 436.82
ΔS°rxn = 29.88 J/K
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