Answer:
(ii) 1s2 2s2 2p6 3s2
Explanation:
Electron Affinity is the energy change that occur when an atom gains an electron.
X₍₉₎ + e⁻ → X⁻ ΔE = Eea
ΔE is change in energy
Eea is electron affinity
Often, electron affinity has negative energy values. The more negative the electron affinity, the easier it is to add an electron to a particular atom. Electron affinity increases across the period in the periodic table. However, there are few exceptions:
1. The electron affinities of group 18 (8A) elements are greater than zero. This is because the atom has a filled valence shell, an addition of electron causes the electron to move to a higher energy shell.
2. The electron affinities of group 2 (2A) elements are more positive because addition of an electron requires it to reside in the previously unoccupied p sub-shell.
3. The electron affinities of group 15 (5A) elements are more positive because addition of an electron requires it to be put in an already occupied orbital.
Applying these consideration to the elements given in the question:
(i) The sum of the electron in 1s²2s² 2p⁶ 3s¹ = 2+2+6+1 = 11 Sodium (Na)
(ii) The sum of the electron in 1s² 2s² 2p⁶ 3s² = 2+2+6+2 = 12 Magnesium (Mg)
(iii) The sum of the electron in 1s² 2s² 2p⁶ 3s² 3p¹ = 2+2+6+2+1 = 13 Aluminium (Al)
(iv) The sum of the electron in 1s² 2s² 2p⁶ 3s² 3p⁴ = 2+2+6+2+4 = 16 Sulfur (S)
(v) The sum of the electron in 1s² 2s² 2p⁶ 3s² 3p⁵ = 2+2+6+2+5 = 17 Chlorine (Cl)
The atom that is expected to have a positive electron affinity is Magnesium which is a group 2A element with electron configuration of 1s² 2s² 2p⁶ 3s².
