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Answer: pH = 1.82

Here is the complete question:

A 20.0-ml sample of 0.150 m koh is titrated with 0.125 m hclo4 solution. Calculate the pH after the following volumes of acid have been added: 30.0 mL.

Explanation: Please see the attachments below

Ver imagen Abdulazeez10
Ver imagen Abdulazeez10

The ph after the following volumes of acid have been added is mathematically given as

pH=1.82

What is the ph value?

Question Parameters:

A 20.0-ml sample of 0.150 m koh is titrated with 0.125 m hclo4 solution.

Generally, the equation for the Chemical Reaction  is mathematically given as

HClO4+KOH--->KClO4+H20

Therefore

3.0*10^{-3} mole of HClO4[H+] will react with 3.0*10^{-3}[oH-] moles of KOH

Hence excess HClO4 is

x=(3.75*10^{-3} 3.0*10^{-3}}

x=0.75*10^{-3}

The final volume is

V=20+30

V=50*10^{-3}

In conclusion, The pH value is

pH = - log [H3O+].

Hence

pH=1.82

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