A bottle in lab is labeled [CoCl2.6H2O] = 0.652 M in 8.433 M HCl. If you determine [CoCl42-] to be 0.129 M at a particular temperature using absorbance measurements, what must be the value of [Co(H2O)62+] in the solution at that temperature?

Respuesta :

Explanation:

Chemical equation for the given reaction is as follows.

     [tex][Co(H_{2}O)_{6}]^{2} + 4Cl^{-} \rightleftharpoons [CoCl_{4}]^{2-} + 6H_{2}O[/tex]

First, we will calculate the moles of [tex]Co^{2+}[/tex] as follows.

       [tex]\frac{0.652 \times 1 mole Co^{2+}}{1 mole [CoCl(H_{2}O)_{6}]^{2+}}[/tex]

         = 0.652 mol [tex]Co^{2+}[/tex]

Therefore,

      [tex]\frac{0.129 \times 1 mole Co^{2+}}{1 mol of CoCl^{2-}_{4}}[/tex]

       = 0.129 moles of [tex]Co^{2+}[/tex]

Now, moles per liter of [tex]Co^{2+}[/tex] which will not react will be calculated as follows.

          0.652 - 0.129

         = 0.523

Thus, we can conclude that there are 0.523 moles of [tex]Co^{2+}[/tex]present per liter.