Answer:
The First-order phase transitions will occur.
Explanation:
The First-order phase transitions are those that involve a latent heat. During such a transition, a system either absorbs or releases a fixed (and typically large) amount of energy per volume while Second order phase transitions occur when a new state of reduced symmetry develops continuously from the disordered (high temperature) phase. The ordered phase has a lower symmetry than the Hamiltonian—the phenomenon of spontaneously broken symmetry.
There are six changes of phase that substances go through: