The temperature of an ideal gas in a sealed 0.1 m3 container is reduced from 430 K to 270 K. The final pressure of the gas is 70 kPa. The molar heat capacity at constant volume of the gas is 28.0 J/mol · K. The work done by the gas is closest to:a) -42


b) -54


c) 54


d) 42


e) 0.00

Respuesta :

Answer:

Thus, the heat absorbed by the gas is closest to 13.97 kJ

Explanation:

First we have to calculate the moles of gas.

Using ideal gas equation:

PV=nRT

where,

P = Pressure of gas = 70 kPa  = 70000 Pa

V = Volume of gas = 0.1m^3

n = number of moles = ?

R = Gas constant = [tex]8.314m^3Pa/mol.K[/tex]

T = Temperature of gas = 270K

Putting values in above equation, we get:

[tex]70000Pa\times 0.1m^3=n\times (8.314m^3Pa/mol.K)\times 270K\\n = 3.118mol[/tex]

Heat released at constant volume is known as internal energy.

The formula used for change in internal energy of the gas is:

[tex]:\Delta Q=\Delta U\\\\\Delta U=nC_v\Delta T\\\\\Delta Q=nC_v(T_2-T_1)[/tex]

where,

[tex]\Delta Q[/tex] = heat at constant volume = ?  

[tex]\Delta U[/tex] = change in internal energy

n = number of moles of gas = 3.118 moles

[tex]C_v[/tex]= heat capacity at constant volume gas = 28.0 J/mol.K

[tex]T_1[/tex]= initial temperature = 430 K

[tex]T_2[/tex] = final temperature = 270 K

Now put all the given values in the above formula, we get:

[tex]\Delta Q=nC_v(T_2-T_1)\Delta Q=(3.118moles)\times (28.0J/mol.K)\times (270-430)K\Delta Q=-13970.19J\\\\=-13.97kJ\\[/tex]

Thus, the heat absorbed by the gas is closest to 13.97 kJ