Calculate the [H+] and pH of a 0.0040 M hydrazoic acid solution. Keep in mind that the Ka of hydrazoic acid is 2.20×10−5. Use the method of successive approximations in your calculations or the quadratic formula.

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Answer:

[tex][H^+]=0.000285[/tex]

[tex]pH=3.55[/tex]

Explanation:

In this, we can with the ionization equation for the hydrazoic acid ([tex]HN_3[/tex]). So:

[tex]HN_3~<->~H^+~+~N_3^-[/tex]

Now, due to the Ka constant value, we have to use the whole equilibrium because this is not a strong acid. So, we have to write the Ka expression:

[tex]Ka=\frac{[H^+][N_3^-]}{[HN_3]}[/tex]

For each mol of [tex]H^+[/tex] produced we will have 1 mol of [tex]N_3^-[/tex]. So, we can use "X" for the unknown values and replace in the Ka equation:

[tex]Ka=\frac{X*X}{[HN_3]}[/tex]

Additionally, we have to keep in mind that [tex]HN_3[/tex] is a reagent, this means that we will be consumed. We dont know how much acid would be consumed but we can express a subtraction from the initial value, so:

[tex]Ka=\frac{X*X}{0.004-X}[/tex]

Finally, we can put the ka value and solve for "X":

[tex]2.2X10^-^5=\frac{X*X}{0.004-X}[/tex]

[tex]2.2X10^-^5=\frac{X^2}{0.004-X}[/tex]

[tex]X= 0.000285[/tex]

So, we have a concentration of 0.000285 for [tex]H^+[/tex]. With this in mind, we can calculate the pH value:

[tex]pH=-Log[H^+]=-Log[0.000285]=3.55[/tex]

I hope it helps!

The [H+] and pH of a 0.0040 M hydrazoic acid solution is 0.000296648 and  3.527759

pH based problem:

What information do we have?

Hydrazoic acid solution = 0.0040 M

Ka of hydrazoic acid = 2.20 × 10⁻⁵

We know that weak acids

[H+] = √( Ka × C)

[H+] = √( 2.2 × 10⁻⁵ × 0.0040)

[H+] = 0.000296648

So,

pH = -log [H+]

pH = -log [0.000296648]

Using log calculator

pH = 3.527759

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