A mixture of Xe, Kr and Ar has a total pressure of 6.70 atm. What is the mole fraction of Kr if the partial pressure of Xe is 1.60 atm and that of Ar is 2.80 atm.

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Answer:

0.343

Explanation:

Step 1: Given data

  • Total pressure of the gaseous mixture (P): 6.70 atm
  • Partial pressure of Xe (pXe): 1.60 atm
  • Partial pressure of Ar (pAr): 2.80 atm

Step 2: Calculate the partial pressure of Kr

The total pressure of the mixture is equal to the sum of the partial pressures of the individual gases.

P = pXe + pAr + pKr

pKr = P - pXe - pAr

pKr = 6.70 atm - 1.60 atm - 2.80 atm

pKr = 2.30 atm

Step 3: Calculate the mole fraction of Kr

We will use the following expression.

X(Kr) = pKr/P

X(Kr) = 2.30 atm/6.70 atm

X(Kr) = 0.343

Considering the Dalton's partial pressure, the mole fraction of Kr is 0.34.

The pressure exerted by a particular gas in a mixture is known as its partial pressure.

So, Dalton's law states that the total pressure of a gas mixture is equal to the sum of the pressures that each gas would exert if it were alone:

[tex]P_{T} =P_{1} +P_{2} +...+P_{n}[/tex] where n is the number of gases.

This relationship is due to the assumption that there are no attractive forces between the gases.

Dalton's partial pressure law can also be expressed in terms of the mole fraction of the gas in the mixture.

So in a mixture of two or more gases, the partial pressure of gas A can be expressed as:

[tex]P_{A} =x_{A} P_{T}[/tex]

In this case, you know:

  • Total pressure= 6.70 atm.
  • Partial pressure of Xe is 1.60 atm.
  • Partial pressure of Ar is 2.80 atm.

So, replacing in the Dalton's partial pressure law:

[tex]P_{T} =P_{Xe} +P_{Ar} +P_{Kr}[/tex]

6.70 atm= 1.60 atm + 2.80 atm + [tex]P_{Kr}[/tex]

6.70 atm- 1.60 atm- 2.80 atm= [tex]P_{Kr}[/tex]

2.30 atm=[tex]P_{Kr}[/tex]

Then: [tex]P_{Kr} =x_{Kr} P_{T}[/tex]

2.30 atm= [tex]x_{Kr}[/tex] 6.70 atm

[tex]x_{Kr}[/tex] =2.30 atm ÷6.70 atm

[tex]x_{Kr}[/tex] = 0.34  

In summary, the mole fraction of Kr is 0.34.

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