Answer: B would be the correct answer
Explanation: You will need to use P1V1/T1=P2V2/T2
So
P1= 81.0kPa /101 =0.799atm
V1=0.4L
T1=25.0C +273.15K= 298.15K
P2= 101kPa /101 = 1atm
V2=0.25L
T2= ?
T2=P2V2T1/P1V1
(1.0atm)(0.25L)(298.15K)/(0.799atm)(0.4L) =233.22K-273.15=-39.92C