Catenation is the property of forming bonds with itself. This property is largely shown by carbon. Hence, it accounts got an enormous number of compounds.
- This is due to the electronic configuration, size, and property of forming covalent bonds.
- Carbon has 4 electrons in its valence shell and forms a covalent bond around itself to complete its octet.
- Carbon is the smallest in nature in the group which means higher nuclear pull on electrons. So, Carbon forms a strong covalent bond.
- They show high dissociation energy, even higher than N-N bonds.
- Other elements due to their larger size do not show this property. Hence, other elements cannot accommodate a large number of atoms around them.
- For example- Sulfur shows the property of catenation with only 8 atoms while carbon form bond with thousands of atoms.
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