The most likely explanation for this phenomenon is that the common ancestor of humans and chimps had 24 chromosomes but during the course of evolution, two human chromosomes fused end to end. So the correct option is A.
Humans and chimps have a DNA which is so similar because these two species are really closely related. The species like Humans, chimps and bonobos have descended from a common ancestor species which lived on earth six or seven million years ago.
Since humans and chimps have gradually evolved from a common ancestor their DNA also passed from generation to generation and thus underwent some changes.
Therefore, these DNA changes are what led to differences between humans and chimps.
Therefore the correct option A.
Read more about common ancestors, here
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