Like any piece of apparatus, an electrolytic cell operates at less than 100% efficiency. A cell depositing Cu from a Cu²⁺bath operates for 10 h with an average current of 5.8 A. If 53.4 g of copper is deposited, at what efficiency is the cell operating?

Respuesta :

The cell is operating at the efficiency of 77.7%

How to Calculate efficiency of electrolytic cell ?

Efficiency = [tex]\frac{\text{mass of Cu deposited}}{W} \times 100\%[/tex]  

where,    

W = mass of Cu that should have been deposited if the electrolytic cell.

Calculation of W:

 [tex]W = \frac{Z \times i \times t}{96486}[/tex]         ....(ii)

Here,

Z = equivalent mass of Cu

since, Cu⁺² + 2e⁻ → Cu

so, change of 2 electrons is taking place, n factor = 2

Equivalent mass of Cu (Z)  = [tex]\frac{\text{mass}}{2}[/tex]

                                            = [tex]\frac{63.5}{2}[/tex]

Given,

i = current = 5.8 A

t = time = 10 h = (10 × 60 × 60) sec

1 Faraday = 95486 C

Now, putting all the value in equation (ii) , we get

 [tex]W = \frac{Z \times i \times t}{96486}[/tex]

W = 63.5 × 5.8 × 10 × 60 × 60

               2 × 96486

W = 68.7

Therefore, from equation (i)

Efficiency = [tex]\frac{\text{mass of Cu deposited}}{W} \times 100\%[/tex]

                = [tex]\frac{53.4}{68.7} \times 100\%[/tex]

                = 77.7 %

Thus from the above conclusion we can say that the cell is operating at an efficiency of 77.7%.

learn more about Electrolytic cells here: https://brainly.com/question/28303387

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