A volcanic eruption melts a large chunk of rock, and allgases are expelled. After cooling, \begin{array}{l}40 \\ 18\end{array} Ar accumulates from the ongoing decay of \begin{array}{l}40 \\ 19\end{array} K in the rock (t₁/₂ = 1.25X10⁹ yr). When a piece of rock is analyzed, it is found to contain 1.38 mmol of ⁴⁰K and 1.14 mmol of ⁴⁰Ar. How long ago did the rock cool?

Respuesta :

1.38 mmol of K-40 are created by the decay of Ar-40. There are 1.14 mmol of Ar-40 left in the world. The initial moles of Ar-40 will be equal to the sum of the moles of K-40 and the remaining moles of Ar-40.

What is half time?

A reaction's half-life is the amount of time needed for a reactant to reach half of its starting concentration or pressure. The half-life is concentration-independent and constant over time for a first-order reaction.

Given:

t(1/2) = 1.25 x 10 ^(9) year

conc K(40) = 1.38 mmol

conc( Ar40) = 1.14

Solution:

n(Ar40)  =  1.38 + 1.50 = 2.88 mmol

half time of the reaction = 1.25 x 10 ^ ( 9) year

k = 0.693/ 1.25 x 10^(9) = 5.54 x 10 ^( -10) year ^(-1)

t = ( 2.303/k ) log ( 2.88/1.14)  = (2.303/5.54 x 10 ^(-10)) log (2.88/1.14)

t = 3.38 x 10^(9) years

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