She feels sorry for Mr. Darcy by pitying him. Jane is less fussy than her sister Elizabeth. She takes men at face value and understands what it's like to be on the losing end of a relationship.
Darcy's first proposal is rejected by Lizzy because, while he claims to loving her, he also says numerous derogatory things about her family and social standing.
Darcy is initially attracted to Elizabeth, but he sees her as unfit socially as a wife; however, his feelings for her are strong enough that he decides to defy convention and marry the woman he loves, fitting him into the mold of a Romantic hero.
If Lizzy had accepted Darcy the first time, it would have been evident that she was marrying for money rather than character, and she would have been a wealthy version of Charlotte Lucas Collins.
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