[tex]-3=2-5\implies -3\mod5=2\mod5[/tex]
When taking a polynomial modulo [tex]n[/tex], you reduce its terms' coefficients modulo [tex]n[/tex], so that, in conjunction with the result above,
[tex]x^2-3x-3\equiv x^2-3x+2\mod5[/tex]
For completeness, the linear term's coefficient should also get reduced in the same way as the constant term, so that
[tex]x^2-3x-3\equiv x^2+2x+2\mod5[/tex]