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Neuron
You didn't provide us with any possible ways? Primary reinforcers are, however, types of reinforcers where they immediately elicit a reward or reward-like behavior once they are applied in a situation. An example would be apple juice. 

Secondary reinforcers on the other hand need to be associated with something for them to become reinforcers or they provide rewards in a non-direct way. An example would be money.

This is the main relationship between them.